Determination of the enthalpy of vaporisation of liquids (with the Cobra3 Basic-Unit)

Product No: P3020411

Principle

The vaporization of a liquid occurs with heat absorption. To determine the enthalpy of vaporization, a known mass of the liquid which is to be investigated is vaporized in a special vaporization vessel in a current of air. The quantity of heat absorbed, which corresponds to the enthalpy of vaporization, can be calorimetrically determined.

Tasks

  1. Determine the molar enthalpy of vaporization of diethyl ether and methanol.
  2. Calculate the molar entropies of vaporization and discuss the results under consideration of Trouton's rule.

What you can learn about

  • Enthalpy of vaporisation
  • Enthalpy of condensation
  • Enthalpy pf sublimation
  • Vapour pressure
  • Entropy of vaporization
  • Clapeyron-Clausius equation
  • Trouton's rule
  • Law of thermodynamics
  • Calorimetry



Materiallist (Excerpt) Product Amount
Set of Precisionl Balance Sartorius CPA 6202S and measure software, 230 V 49226-88 1
Set of Precision Balance Sartorius CPA 623S and measure software, 230 V 49224-88 1
Set calorimetry, 230 V 43030-88 1
Cobra3 Data acquisition set for set calorimetry 43030-30 1
Evaporation vessel for calorim. 04405-00 1
Sec.bottle500ml,2xGl18/8,1x25/12 34170-01 1
Retort stand, 210 mm × 130 mm, h = 500 mm 37692-00 1
Spring manometer, 0...-1000 mbar 34170-02 1
Water jet pump, plastic 02728-00 1
Water, distilled 5 l 31246-81 1
Stopcock,3-way,t-shaped, glass 36731-00 1
Air control valve 37003-00 1
Methanol 500 ml 30142-50 1
Diethyl ether 250 ml 30007-25 1
Separator f.magnetic bars 35680-03 1
Universal clamp 37715-00 2
Cannula 0.9x70mm, Luer, 20 pcs 02597-04 1
Syringe 20ml, Luer, 10 pcs 02591-03 1
Rubber tubing,vacuum,i.d.6mm 39286-00 1
Right angle clamp 37697-00 2
Rubber caps, 10 pcs 39275-03 1
Erlenmeyer flask,wide neck,250ml 36134-00 1
Wash bottle, plastic, 500 ml 33931-00 1
Glass tube, right-angled 36701-07 1
Rubber tubing, i.d. 6 mm 39282-00 1
Hose clip f.12-20 diameter tube 40995-00 5
Laboratory Experiments Physics, Chemistry, Biology andApplied Sciences, CD-ROM, incl. operating manuals 16502-42 1

Literature for this article als follows

Title Product Language
TESS expert Handbook Laboratory Experiments Chemistry 16504-12 ENG

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Product No: P3020411

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