Determination of the hydration enthalpy of an electrolyte (solution enthalpy) (with the Cobra3 Basic-Unit)

Product No: P3020711

Principle

When a solid electrolyte dissolves in water, a positive or negative heat effect occurs as a result of the destruction of the crystal lattice and the formation of hydrated ions. The enthalpy of hydration of copper sulphate can be calculated from the different heats of reaction measured when anhydrous and hydrated copper sulphate are separately dissolved in water.

Tasks

  1. Record temperature-time curves for the dissolution of anhydrous copper sulphate and hydrated copper sulphate in water.
  2. Calculate the hydration enthalpy of anhydrous copper(II)sulphate.

What you can learn about

  • Integral enthalpy of solution
  • Hess's law
  • Lattice energy
  • Ion solvation
  • Calorimetry



Materiallist (Excerpt) Product Amount
Set of Precisionl Balance Sartorius CPA 6202S and measure software, 230 V 49226-88 1
Set calorimetry, 230 V 43030-88 1
Cobra3 Data acquisition set for set calorimetry 43030-30 1
Desiccator, wertex, diam. 150 mm 34126-00 1
Butane burner, Labogaz 206 type 32178-00 1
Silica gel,orange,granular,500 g 30224-50 1
Copper-II sulphate,anhydr. 250 g 31495-25 1
Water, distilled 5 l 31246-81 1
Silicon grease Molykote, 50 g 31863-05 1
Porcelain plate f.desiccator150mm 32474-00 1
Copper-II sulphate,cryst. 250 g 30126-25 1
Supp.rod stainl.st.,50cm,M10-thr. 02022-20 1
Separator f.magnetic bars 35680-03 1
Mortar with pestle, 150 ml, porcelain 32604-00 1
Tripod,ring d=140 mm, h=240 mm 33302-00 1
Porcelain dish 140ml, d 100mm 32518-00 1
Crucible tongs,200mm,stainl.steel 33600-00 1
Glass beaker DURAN®, tall, 50 ml 36001-00 2
Spoon, special steel 33398-00 1
Wire gauze 160 mm x 160 mm, ceramic cen. 33287-01 1
Butane cartridge C206, without valve 47535-00 1
Wash bottle, plastic, 500 ml 33931-00 1
Powder funnel, upper dia. 65mm 34472-00 1
Laboratory Experiments Physics, Chemistry, Biology andApplied Sciences, CD-ROM, incl. operating manuals 16502-42 1

Literature for this article als follows

Title Product Language
TESS expert Handbook Laboratory Experiments Chemistry 16504-12 ENG

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Product No: P3020711

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