Freezing point depression

Product No: P3021101

Principle

The freezing point of a solution is lower than that of the pure solvent. The depression of the freezing point can be determined experimentally using a suitable apparatus (cryoscopy). If the cryoscopy constants of the solvent are known, the molecular mass of the substance dissolved can be determined.

Tasks

  1. Determine the size of freezing point depression after dissolving a strong electrolyte (NaCl) in water. By comparing the experimental value with the theoretical one predicted for this concentration, determine the number of ions into which the electrolyte dissociates.
  2. Determine the molar mass of a non-electrolyte (hydroquinone) from the value of freezing point depression.

What you can learn about

  • Raoult's law
  • Cryoscopic constant
  • Chemical potential
  • Gibbs-Helmholtz equation
  • Concentration ratio
  • Degree of dissociation
  • Van't Hoff factor

 




Materiallist (Excerpt) Product Amount
Set of Precision Balance Sartorius CPA 623S and measure software, 230 V 49224-88 1
Temperature meter digital, 4-2 13617-93 1
Magnetic stirrer MR Hei-Standard 35750-93 1
App.for freezing point depr. 36821-00 1
Temp. probe, immersion type, Pt100, stainless steel, -20...+300°C 11759-01 2
Pellet press for calorimeter 04403-04 1
Gasket for GL25, 12mm hole, 10pcs 41243-03 1
Stopwatch, digital, 1/100 s 03071-01 1
Hydroquinone 250 g 30089-25 1
Water, distilled 5 l 31246-81 1
Protective sleeves f.temp.probe,2 11762-05 1
Sodium chloride, 500 g 30155-50 1
Denaturated alcohol (spirit for burning), 1000 ml 31150-70 1
Supp.rod stainl.st.,50cm,M10-thr. 02022-20 1
Pipettor 36592-00 1
Universal clamp 37715-00 2
Glass beaker DURAN®, short, 1000 ml 36017-00 1
Mortar w. pestle, 70ml, porcelain 32603-00 2
Pasteur pipettes, 250 pcs 36590-00 1
Weighing dishes, square shape, 84 x 84 x 24 mm, 25 pcs. 45019-25 1
Right angle clamp 37697-00 2
Volumetric pipette, 50 ml 36581-00 1
Rubber caps, 10 pcs 39275-03 1
Microspoon, steel 33393-00 1
Spoon, special steel 33398-00 1
Magnetic stirring bar 30 mm, cylindrical 46299-02 1
Wash bottle, plastic, 500 ml 33931-00 1
Glass rod,boro 3.3,l=300mm, d=8mm 40485-06 1
Funnel, plastic, dia.50mm 36890-00 1
Laboratory Experiments Physics, Chemistry, Biology andApplied Sciences, CD-ROM, incl. operating manuals 16502-42 1

Literature for this article als follows

Title Product Language
TESS expert Handbook Laboratory Experiments Chemistry 16504-12 ENG

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Product No: P3021101

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