Determination of the enthalpy of combustion with a calorimetric bomb

Product No: P3021401

Principle

The  bomb calorimeter is used to completely burn substances in an excess of oxygen.The heat of combustion released is absorbed by the calorimetric vessel in which the bomb is immersed, and results in a temperature increase ΔT. The heat capacity of the system is first determined by adding a defined amount of heat from the combustion of benzoic acid. The combustion of the naphthalene is subsequently performed under the same conditions.

Tasks

  1. Determine the enthalpy of combustion of naphtalene using a bomb calorimeter.
  2. Calculate the enthalpy of formation of naphthalene from the enthalpy of combusting unsing Hess's law.

What you can learn about

  • First law of thermodynamics
  • Hess' law of constant heat summation
  • Enthalpy of combustion
  • Enthalpy of formation
  • Heat capacity



Materiallist (Excerpt) Product Amount
Set of Precisionl Balance Sartorius CPA 6202S and measure software, 230 V 49226-88 1
Set of Precision Balance Sartorius CPA 623S and measure software, 230 V 49224-88 1
Calorimetric bomb 04403-00 1
Temperature meter digital, 4-2 13617-93 1
Power supply, universal 13500-93 1
Magnetic stirrer MR Hei-Standard 35750-93 1
Calorimeter, transparent, volume appr. 1200 ml 04402-00 1
Steel cylinder oxygen, 2l, filled 41778-00 1
Temp. probe, immersion type, Pt100, stainless steel, -20...+300°C 11759-01 1
Reducing valve f.oxygen 33482-00 1
Table stand f.2 l steel cylinders 41774-00 1
Pressure tube with fittings 39299-00 1
Pellet press for calorimeter 04403-04 1
Test vessel f.calorim.bomb,10 pcs 04403-03 1
Stopwatch, digital, 1/100 s 03071-01 1
Water, distilled 5 l 31246-81 1
Naphthalene white 250 g 48299-25 1
Benzoic acid 100 g 30251-10 1
Wrench for steel cylinders 40322-00 1
Supp.rod stainl.st.,50cm,M10-thr. 02022-20 1
Universal clamp 37715-00 1
Magnetic stirring bar oval,30mm 35680-04 1
Mortar w. pestle, 70ml, porcelain 32603-00 1
Iron wire, d = 0.2 mm, l = 100 m 06104-00 1
Weighing dishes, square shape, 84 x 84 x 24 mm, 25 pcs. 45019-25 1
Scissors,straight,blunt,l 140mm 64625-00 1
Right angle clamp 37697-00 1
Connecting cord, 32 A, 750 mm, black 07362-05 2
Graduated vessel, 1 l, with handle 36640-00 1
Microspoon, steel 33393-00 1
Wash bottle, plastic, 500 ml 33931-00 1
Funnel, plastic, dia.50mm 36890-00 1
Laboratory Experiments Physics, Chemistry, Biology andApplied Sciences, CD-ROM, incl. operating manuals 16502-42 1

Literature for this article als follows

Title Product Language
TESS expert Handbook Laboratory Experiments Chemistry 16504-12 ENG

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Product No: P3021401

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