Determination of the activity coefficient by a conductivity measurement

Product No: P3060801

Principle

The equivalent conductivity of strong electrolytes depends on their concentration. The quotient of the equivalent conductivity at a certain concentration and the equivalent conductivity at infinite dilution is called the conductivity coefficient, which is tthe result of interionic action. 

Tasks

Measure the specific conductivities of various potassium chloride and calcium chloride solutions and calculate the equivalent conductivities. Determine the equivalent conductivities at infinite dilution using the Kohlrausch equation and calculate the conductivity coefficients.

What you can learn about

  • Equivalent conductivity
  • Ion mobility
  • Conductivity
  • Interionic action



Materiallist (Excerpt) Product Amount
Set of Analytical Balance Sartorius CPA 224S and measure software, 230 V 49221-88 1
Digital conductivity meter 13701-93 1
Desiccator, wertex, diam. 150 mm 34126-00 1
Conductivity temperature probe Pt1000 13701-01 1
Magnetic stirrer Mini / MST 47334-93 1
Retort stand, h 750 mm 37694-00 1
Silica gel,orange,granular,500 g 30224-50 1
Water, distilled 5 l 31246-81 1
Silicon grease Molykote, 50 g 31863-05 1
Protection sleeve for electrode with a diameter of 12 mm 37651-15 1
Porcelain plate f.desiccator150mm 32474-00 1
Pipette dish 36589-00 1
Potassium chloride 250 g 30098-25 1
Calcium chloride, granul. 250 g 48021-25 1
Stand.solu.1413æS/cm(25øC), 460ml 47070-02 1
Volumetric flask 500 ml, IGJ19/26 36551-00 2
Pipettor 36592-00 1
Volumetric flask 250 ml, IGJ14/23 36550-00 6
Pasteur pipettes, 250 pcs 36590-00 1
Spring balance holder 03065-20 1
Weighing dishes, square shape, 84 x 84 x 24 mm, 25 pcs. 45019-25 1
Support rod with hole, stainless steel, 10 cm 02036-01 1
Right angle clamp 37697-00 4
Volumetric pipette, 50 ml 36581-00 2
Cristallizing dish,boro3.3, 320ml 46243-00 1
Volumetric pipette, 25 ml 36580-00 2
Rubber caps, 10 pcs 39275-03 1
Glass beaker DURAN®,tall, 150 ml 36003-00 8
Glass beaker DURAN®, tall, 50 ml 36001-00 2
Funnel, glass, top dia. 80 mm 34459-00 2
Volumetric pipette, 5 ml 36577-00 2
Spoon, special steel 33398-00 1
Magnetic stirring bar 30 mm, cylindrical 46299-02 1
Wash bottle, plastic, 500 ml 33931-00 1
Laboratory Experiments Physics, Chemistry, Biology andApplied Sciences, CD-ROM, incl. operating manuals 16502-42 1

Literature for this article als follows

Title Product Language
TESS expert Handbook Laboratory Experiments Chemistry 16504-12 ENG

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Product No: P3060801

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