Concentration cells without transport: Determination of thesolubility products of silver halides

Product No: P3061001

Principle:

A concentration cell is constructed from two half-cells which are identical, except that the concentration of the ionic species to which the electrode is sensitive is different in the two sides of the cell. Such a cell may be used to measure the solubility product of a sparingly soluble salt. In one half-cell the concentration of  these ions is known, in the other it is determined by the solubility product of the salt under investigation. The ratio of the two concentrations (more accurately, activities) determines the e.m.f. of the cell.

Tasks:

Use a concentration cell made from two Ag(S) l Ag+(ag) electrodes, to determine the solubility product of the three silver halides AgCl, AgBr and AgI.

What you can learn about:

  • Concentration cells without transport
  • Electromotive force
  • Salt bridge
  • Liquid junction and diffucison potentials



Materiallist (Excerpt) Product Amount
Set of Analytical Balance Sartorius CPA 224S and measure software, 230 V 49221-88 1
Digital pH-meter 13702-93 1
Temperature probe Pt-1000 13702-01 1
Silver nitrate, cryst. 15 g 30222-00 1
Silver foil, 150X150X0.1mm, 25 g 31839-04 1
Clay pins, d = 8 mm, l = 15 mm, 2 pcs 32486-00 1
Retort stand, h 750 mm 37694-00 1
Holder for two electrodes 45284-01 1
Nitric acid , 65% 1000 ml 30213-70 1
Salt bridge 37684-00 1
Water, distilled 5 l 31246-81 1
Potassium iodide 50 g 30104-05 1
Pipette dish 36589-00 1
Potassium nitrate 250 g 30106-25 1
Potassium chloride 250 g 30098-25 1
Potassium bromide 100 g 30258-10 1
Pipettor 36592-00 1
Volumetric flask 250 ml, IGJ14/23 36550-00 12
Scissors, straight,180 mm 64798-00 1
Pasteur pipettes, 250 pcs 36590-00 1
Spring balance holder 03065-20 1
Weighing dishes, square shape, 84 x 84 x 24 mm, 25 pcs. 45019-25 1
Right angle clamp 37697-00 1
Rubber caps, pack of 20 02615-03 1
Alligator clips, bare, 10 pcs 07274-03 1
Volumetric pipette, 25 ml 36580-00 8
Graduated cylinder 100 ml 36629-00 1
Rubber caps, 10 pcs 39275-03 1
Connecting cord, 32 A, 500 mm, red 07361-01 1
Connecting cord, 32 A, 500 mm, blue 07361-04 1
Glass beaker DURAN®,tall, 150 ml 36003-00 2
Glass beaker DURAN®, tall, 50 ml 36001-00 12
Glass beaker DURAN®, tall, 250 ml 36004-00 1
Cannula 0.6x60 mm, Luer, 20 pcs 02599-04 1
Silicone tubing i.d. 7mm 39296-00 1
Spoon, special steel 33398-00 1
Syringe 10ml, Luer, 10 pcs 02590-03 1
Funnel, glass, top dia. 55 mm 34457-00 4
Wash bottle, plastic, 500 ml 33931-00 1
Graduated pipette, 5 ml 36598-00 1
Glass rod,boro 3.3,l=200mm, d=5mm 40485-03 1
Laboratory Experiments Physics, Chemistry, Biology andApplied Sciences, CD-ROM, incl. operating manuals 16502-42 1

Literature for this article als follows

Title Product Language
TESS expert Handbook Laboratory Experiments Chemistry 16504-12 ENG

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Product No: P3061001

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