Determination of diffusion potentials

Product No: P3061101

Principle

An electrochemical potential establishes itself at the interface between two solutions of different ion concentrations. The magnitude of this is determined by the concentration ratio and the transference numbers of the ions involved. This potential difference can be measured as a function of the concentration at semi-permeable and ion-selective membranes.

Tasks

  1. Measure the diffusion potential as a function of the concentration gradient at a cellophane membrane and at a cation-selective membrane.
  2. Determine the transference numbers of the ions in HCl, naCl and KCl.

What you can learn about

  • Concentration cells with transport
  • Transference numbers
  • Semi-permeable membrane
  • Selectively permeable membrane
  • Nernst equation

 




Materiallist (Excerpt) Product Amount
Set of Precision Balance Sartorius CPA 623S and measure software, 230 V 49224-88 1
Osmosis and electrochemistry chamber 35821-00 1
Digital thermometer, NiCr-Ni, -50...+1300°C 07050-00 1
Magnetic stirrer Mini / MST 47334-93 1
Digital multimeter 2010 07128-00 1
Gasket for GL25, 12mm hole, 10pcs 41243-03 1
Retort stand, h 750 mm 37694-00 1
Reference electrode, AgCl 18475-00 2
Immersion probe NiCr-Ni, steel, -50...400°C 13615-03 1
Membrane, permeable for cations, 5pcs 31504-02 1
Hydrochloric acid,0.1M 1000 ml 48452-70 1
Stopwatch, digital, 1/100 s 03071-01 1
Water, distilled 5 l 31246-81 1
Volumetric flask 1000ml, IGJ24/29 36552-00 6
Pipette dish 36589-00 1
Potassium chloride 250 g 30098-25 1
Sodium chloride, 500 g 30155-50 1
Pipettor 36592-00 1
Universal clamp 37715-00 1
Cellophane, 300x200 mm, 5 sheets 32987-00 1
Pasteur pipettes, 250 pcs 36590-00 1
Volumetric flask 100 ml, IGJ12/21 36548-00 6
Scissors,straight,pointed,l 110mm 64623-00 1
Right angle clamp 37697-00 1
Volumetric pipette, 50 ml 36581-00 3
Rubber caps, 10 pcs 39275-03 1
Glass beaker DURAN®, tall, 100 ml 36002-00 4
Glass beaker DURAN®, tall, 250 ml 36004-00 1
Volumetric pipette, 20 ml 36579-00 3
Cannula 0.6x60 mm, Luer, 20 pcs 02599-04 1
Funnel, glass, top dia. 80 mm 34459-00 2
Volumetric pipette, 10 ml 36578-00 1
Volumetric pipette, 5 ml 36577-00 1
Spoon, special steel 33398-00 1
Syringe 1ml, Luer, 10 pcs 02593-03 1
Wash bottle, plastic, 500 ml 33931-00 1
Volumetric pipette, 1 ml 36575-00 2
Magn.stirring bar 15mm, cyl. 46299-01 1
Laboratory Experiments Physics, Chemistry, Biology andApplied Sciences, CD-ROM, incl. operating manuals 16502-42 1

Literature for this article als follows

Title Product Language
TESS expert Handbook Laboratory Experiments Chemistry 16504-12 ENG

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Product No: P3061101

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