Distribution equilibrium

Product No: P3030701

Principle

At constant temperature and under constant pressure, a dissolved substance distributes itself between two immiscible liquids in a constant concentration ratio. This ratio is equal to the partition coefficient (distribution coefficient) of the substance examined in the given two-phase system.

Tasks

  1. Measure the extinction of various concentrated solutions of trans-azobenzene in acetonitrile at constant wavelength. Subsequently determine the equilibrium concentrations (extinctions) of trans-azobenzene in the system n-heptane / acetonitrile after single and repeated distribution at constant temperature.
  2. Calculate the partition coefficients and effectiveness of the extractions from the experimental data and compare them.

What you can learn about

  • Principles of thermodynamics
  • Partial molar free enthalpy (chemical potential)
  • Equilibrium between phases
  • Distribution and extraction
  • Nernst distribution equation
  • Lambert-Beer law
  • Photometry



Materiallist (Excerpt) Product Amount
Set of Precision Balance Sartorius CPA 623S and measure software, 230 V 49224-88 1
Spectrophotometer S800, 330...800 nm 35600-99 1
Trans-azobenzene f. synth., 100 g 31064-10 1
Cells f.spectrophotometer, 2 pcs 35664-02 1
Separatory funnel 1000 ml 35850-04 1
Acetonitrile 1000 ml 30000-70 1
Retort stand, h 750 mm 37694-00 1
Separatory funnel 250 ml pear-sh. 36884-00 4
Thermometer -10...+50 C 38034-00 1
n-heptane, extra pure 250 ml 31366-25 1
Pipette dish 36589-00 1
Pipettor 36592-00 1
Volumetric flask 250 ml, IGJ14/23 36550-00 1
Erlenmeyer flask,narrow n.,1000ml 36122-00 1
Pasteur pipettes, 250 pcs 36590-00 1
Weighing dishes, square shape, 84 x 84 x 24 mm, 25 pcs. 45019-25 1
Volumetric flask 50 ml, IGJ12/21 36547-00 4
Right angle clamp 37697-00 2
Support ring, i.d. 70mm, 37721-01 2
Erlenmeyer flask,narrow n.,500 ml 36121-00 1
Rubber caps, 10 pcs 39275-03 1
Glass beaker DURAN®, tall, 100 ml 36002-00 2
Erlenmeyer flask,narrow n.,250 ml 36124-00 1
Volumetric pipette, 20 ml 36579-00 2
Microspoon, steel 33393-00 1
Volumetric pipette, 10 ml 36578-00 1
Funnel, glass, top dia. 55 mm 34457-00 1
Wash bottle, plastic, 500 ml 33931-00 1
Rubber stopper,d=44/36mm,w/o hole 39262-00 1
Rubber stopper, d = 35 / 29 mm, without hole 39259-00 2
Laboratory Experiments Physics, Chemistry, Biology andApplied Sciences, CD-ROM, incl. operating manuals 16502-42 1

Literature for this article als follows

Title Product Language
TESS expert Handbook Laboratory Experiments Chemistry 16504-12 ENG

back to corresponding listview

Product No: P3030701

Recommend this page  ∇

X-ray expert unit

This product is a world first

PHYWE presents the new x-ray unit: innovative technology, top safety, maximum comfort!

More